Chromatographic Techniques for the Detection and Identification of Olive Oil Adulteration

  1. Musfra Khursheed 1
  2. Ali Ahmad 2
  3. Noor, Shab E. 3
  4. García Del Moral Garrido, Luis F. 4
  5. Martos Núñez, Vanessa 4
  1. 1 Bahauddin Zakariya University
    info

    Bahauddin Zakariya University

    Multan, Pakistán

    ROR https://ror.org/05x817c41

  2. 2 Universidad Politécnica de Valencia
    info

    Universidad Politécnica de Valencia

    Valencia, España

    ROR https://ror.org/01460j859

  3. 3 Universidad de Jaén
    info

    Universidad de Jaén

    Jaén, España

    ROR https://ror.org/0122p5f64

  4. 4 Universidad de Granada
    info

    Universidad de Granada

    Granada, España

    ROR https://ror.org/04njjy449

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Revista:
ReiDoCrea: Revista electrónica de investigación y docencia creativa

ISSN: 2254-5883

Ano de publicación: 2024

Volume: 13

Páxinas: 1-9

Tipo: Artigo

DOI: 10.30827/DIGIBUG.86578 DIALNET GOOGLE SCHOLAR lock_openAcceso aberto editor

Outras publicacións en: ReiDoCrea: Revista electrónica de investigación y docencia creativa

Resumo

Olive oil stands out as one of the most beneficial oils for human health, offering preventive measures against a spectrum of health issues, including cardiovascular problems, cancer, osteoporosis, and various chronic diseases. However, the surging demand for olive oil has led to its susceptibility to adulteration with cheaper oils, such as soybean, peanut, hazelnut, and sunflower oil. Notably, extra virgin olive oil (EVOO), commanding a premium price, is particularly prone to adulteration with lower-cost alternatives. This adulteration poses a significant risk to health, necessitating the development of methods to detect and separate these impurities, thereby ensuring the quality and safety of olive oil. In order to address this concern, chromatographic techniques have emerged as pivotal tools in the purification and detection of adulterants in olive oil. Commonly employed methods include Thin Layer Chromatography (TLC), Gas Chromatography (GC), Liquid Chromatography (LC), and High-Performance Liquid Chromatography (HPLC). These techniques play a crucial role in differentiating between pure and impure olive oil in the market. This article focuses on the most prospective chromatographic methods for the detection and identification adulteration in olive oil. The outcomes of this research have the potential to pave the way for new directions in food security research, contributing to overall sustainability. Moreover, the insights gained from this study can be valuable for young students, serving as a concise reference for analytical methods in this field.

Referencias bibliográficas

  • Aboul‐Enein, H. Y., El‐Awady, M. I., Heard, C. M., & Nicholls, P. J. (1999). Application of thin‐layer chromatography in enantiomeric chiral analysis—an overview. Biomedical Chromatography, 13(8), 531-537.
  • Al-Bukhaiti, W. Q., Noman, A., Qasim, A. S., & Al-Farga, A. (2017). Gas chromatography: Principles, advantages and applications in food analysis. International Journal of Agriculture Innovations and Research, 6(1), 2319-1473.
  • Al-Ismail, K. M., Alsaed, A. K., Ahmad, R., & Al-Dabbas, M. (2010). Detection of olive oil adulteration with some plant oils by GLC analysis of sterols using polar column. Food Chemistry, 121(4), 1255-1259.
  • Aparicio, R., & Harwood, J. (2013). Handbook of olive oil. Springer.
  • Bakre, S. M., Gadmale, D. K., Toche, R. B., & Gaikwad, V. B. (2015). Rapid determination of alpha tocopherol in olive oil adulterated with sunflower oil by reversed phase high-performance liquid chromatography. Journal of Food Science and Technology, 52(5), 3093-3098. https://doi.org/10.1007/s13197-014-1309-7
  • Boskou, D. (2011). 9–Olive oil. Vegetable oils in food technology. Composition, properties and uses. Wiley-Blackwell, Oxford, 243-269.
  • Broeckhoven, K., & Desmet, G. (2020). Advances and innovations in liquid chromatography stationary phase supports. Analytical Chemistry, 93(1), 257-272.
  • Calabriso, N., Scoditti, E., Pellegrino, M., & Annunziata Carluccio, M. (2015). Chapter 13 Olive Oil. In V. R. Preedy & R. R. Watson (Eds.), The Mediterranean Diet (pp. 135-142). Academic Press. https://doi.org/https://doi.org/10.1016/B978-0-12-407849-9.00013-
  • Calabriso, N., Scoditti, E., Pellegrino, M., & Carluccio, M. A. (2015). Olive oil. In The Mediterranean Diet (pp. 135-142). Elsevier.
  • Calvano, C. D., Aresta, A., & Zambonin, C. G. (2010). Detection of hazelnut oil in extra‐virgin olive oil by analysis of polar components by micro‐solid phase extraction based on hydrophilic liquid chromatography and MALDI‐ToF mass spectrometry. Journal of mass spectrometry, 45(9), 981-988.
  • Casadei, E., Valli, E., Panni, F., Donarski, J., Farrús Gubern, J., Lucci, P., Conte, L., Lacoste, F., Maquet, A., Brereton, P., Bendini, A., & Gallina Toschi, T. (2021). Emerging trends in olive oil fraud and possible countermeasures. Food Control, 124, 107902. https://doi.org/10.1016/j.foodcont.2021.107902
  • Cercaci, L., Rodriguez-Estrada, M. T., & Lercker, G. (2003a). Solidphase extraction–thin-layer chromatography–gas chromatography method for the detection of hazelnut oil in olive oils by determination of esterified sterols. Journal of Chromatography A, 985(1-2), 211- 220.
  • Cercaci, L., Rodriguez-Estrada, M. T., & Lercker, G. (2003b). Solidphase extraction–thin-layer chromatography–gas chromatography method for the detection of hazelnut oil in olive oils by determination of esterified sterols. Journal of Chromatography A, 985(1), 211-220.
  • Choudhary, A., Gupta, N., Hameed, F., & Choton, S. (2020). An overview of food adulteration: Concept, sources, impact, challenges and detection. International Journal of Chemical Studies, 8(1), 2564-2573.
  • Christopoulou, E., Lazaraki, M., Komaitis, M., & Kaselimis, K. (2004). Effectiveness of determinations of fatty acids and triglycerides for the detection of adulteration of olive oils with vegetable oils. Food Chemistry, 84(3), 463-474.
  • Ciura, K., Dziomba, S., Nowakowska, J., & Markuszewski, M. J. (2017). Thin layer chromatography in drug discovery process. Journal of Chromatography A, 1520, 9-22. https://doi.org/10.1016/j.chroma.2017.09.015
  • Dionisi, F., Prodolliet, J., & Tagliaferri, E. (1995). Assessment of olive oil adulteration by reversed-phase high-performance liquid chromatography/amperometric detection of tocopherols and tocotrienols. Journal of the American Oil Chemists’ Society, 72, 1505-1511.
  • Drira, M., Guclu, G., Portolés, T., Jabeur, H., Kelebek, H., Selli, S., & Bouaziz, M. (2021). Safe and fast fingerprint aroma detection in adulterated extra virgin olive oil using gas chromatography– olfactometry-mass spectrometry combined with chemometrics. Food Analytical Methods, 14, 2121-2135.
  • Fasciotti, M., & Netto, A. D. P. (2010). Optimization and application of methods of triacylglycerol evaluation for characterization of olive oil adulteration by soybean oil with HPLC–APCI-MS–MS. Talanta, 81(3), 1116-1125.
  • Foscolou, A., Critselis, E., & Panagiotakos, D. (2018). Olive oil consumption and human health: A narrative review. Maturitas, 118, 60-66.
  • Frankel, E., Mailer, R., Wang, S., Shoemaker, C., Guinard, J., Flynn, J., & Sturzenberger, N. (2011). Evaluation of extra-virgin olive oil sold in California. Final Report, University of California, Davis, Olive Center at the Robert Mondavi Institute, Davis, CA.
  • Fuentes de Mendoza, M., De Miguel Gordillo, C., Marín Expóxito, J., Sánchez Casas, J., Martínez Cano, M., Martín Vertedor, D., & Franco Baltasar, M. N. (2013). Chemical composition of virgin olive oils according to the ripening in olives. Food chemistry, 141(3), 2575-2581. https://doi.org/10.1016/j.foodchem.2013.05.074
  • Gupta, M. K., & Biswas, P. K. (2023). Chromatography: Basic principle, types, and applications. In Basic Biotechniques for Bioprocess and Bioentrepreneurship (pp. 173-182). Elsevier.
  • Hage, D. (2018). Chromatography. Principles and applications of clinical mass spectrometry: small molecules, peptides, and pathogens. Rifai N, Horvath AR, Wittwer C, Editors.
  • Kapoulas, V., & Passaloglou‐Emmanouilidou, S. (1981). Detection of adulteration of olive oil with seed oils by a combination of column and gas liquid chromatography. Journal of the American Oil Chemists' Society, 58(6), 694-697.
  • Kaur, G., & Sharma, S. (2018). Gas chromatography-a brief review. International Journal of Information and Computing Science, 5(7), 125-131.
  • Kiritsakis, A., & Markakis, P. (1988). Olive oil: a review. Advances in food Research, 31, 453-482.
  • Marcos Lorenzo, I., Pérez Pavón, J. L., Fernández Laespada, M. E., García Pinto, C., & Moreno Cordero, B. (2002). Detection of adulterants in olive oil by headspace–mass spectrometry. Journal of Chromatography A, 945(1), 221-230. https://doi.org/10.1016/S0021-9673(01)01502-3
  • McNair, H. M., Miller, J. M., & Snow, N. H. (2019). Basic gas chromatography. John Wiley & Sons.
  • Medina, S., Auñón, D., Lehoux, J., Durand, T., Crauste, C., & GilIzquierdo, Á. (2022). Hydroxytyrosol fatty acid esters as new candidate markers for detecting olive oil inadequate storage conditions by UHPLC-QqQ-MS/MS. Microchemical Journal, 181, 107656.
  • Meenu, M., Cai, Q., & Xu, B. (2019). A critical review on analytical techniques to detect adulteration of extra virgin olive oil. Trends in Food Science & Technology, 91, 391-408.
  • Mildner-Szkudlarz, S., & Jeleń, H. H. (2008). The potential of different techniques for volatile compounds analysis coupled with PCA for the detection of the adulteration of olive oil with hazelnut oil. Food Chemistry, 110(3), 751-761.
  • Navratilova, K., Hurkova, K., Hrbek, V., Uttl, L., Tomaniova, M., Valli, E., & Hajslova, J. (2022). Metabolic fingerprinting strategy: Investigation of markers for the detection of extra virgin olive oil adulteration with soft-deodorized olive oils. Food Control, 134, 108649.
  • Patil, H. D., Patil, C. B., Patil, V. V., Patil, P. S., & Pawar, A. R. (2023). A Brief Review on Gas Chromatography. Asian Journal of Pharmaceutical Analysis, 13(1), 47-52.
  • Rocco, A., & Fanali, S. (2009). Analysis of phytosterols in extravirgin olive oil by nano-liquid chromatography. Journal of Chromatography A, 1216(43), 7173-7178.
  • Ruiz-Samblás, C., Marini, F., Cuadros-Rodríguez, L., & González Casado, A. (2012). Quantification of blending of olive oils and edible vegetable oils by triacylglycerol fingerprint gas chromatography and chemometric tools. Journal of Chromatography B, 910, 71-77.
  • Salivaras, E., & McCurdy, A. R. (1992). Detection of olive oil adulteration with canola oil from triacylglycerol analysis by reversedphase high-performance liquid chromatography. Journal of the American Oil Chemists Society, 69(9), 935-938. https://doi.org/10.1007/BF02636347
  • Scott, P., Lawrence, J., & Van Walbeek, W. (1970). Detection of mycotoxins by thin-layer chromatography: application to screening of fungal extracts. Applied Microbiology, 20(5), 839-842.
  • Shockcor, J. (2017). HPLC–NMR Pharmaceutical Applications. Du Pont Pharmaceuticals Co. In: Newark, NJ, USA: Elsevier.
  • Tanno, R., Kato, S., Shimizu, N., Ito, J., Sato, S., Ogura, Y., Sakaino, M., Sano, T., Eitsuka, T., & Kuwahara, S. (2020). Analysis of oxidation products of α-tocopherol in extra virgin olive oil using liquid chromatography–tandem mass spectrometry. Food Chemistry, 306, 125582.
  • Uncu, O., & Ozen, B. (2020). Importance of some minor compounds in olive oil authenticity and quality. Trends in Food Science & Technology, 100, 164-176.
  • Vanstone, N., Moore, A., Martos, P., & Neethirajan, S. (2018). Detection of the adulteration of extra virgin olive oil by near-infrared spectroscopy and chemometric techniques. Food Quality and Safety, 2(4), 189-198.
  • Webster, L., Simpson, P., Shanks, A. M., & Moffat, C. F. (2000). The authentication of olive oil on the basis of hydrocarbon concentration and composition. Presented at SAC 99, Dublin, Ireland, July 25–30, 1999. Analyst, 125(1), 97-104.
  • Yang, H., & Irudayaraj, J. (2001). Comparison of near-infrared, Fourier transform-infrared, and Fourier transform-Raman methods for determining olive pomace oil adulteration in extra virgin olive oil. Journal of the American Oil Chemists' Society, 78, 889-895.
  • Zabaras, D., & Gordon, M. (2004). Detection of pressed hazelnut oil in virgin olive oil by analysis of polar components: improvement and validation of the method. Food Chemistry, 84(3), 475-483.
  • Zeeuw, J. d., & Luong, J. (2002). Developments in stationary phase technology for gas chromatography. TrAC Trends in Analytical Chemistry, 21(9), 594-607. https://doi.org/10.1016/S0165-9936(02)00809-9
  • Zhou, X., Zhang, Q., Chen, X., Li, X., & Han, C. (2021). In-situ assessment of olive oil adulteration with soybean oil based on thermogravimetric-gas chromatography/mass spectrometry combined with chemometrics. Food Control, 130, 108251.
Fonte de datos: Dialnet