MATERIALES ORGÁNICOS FUNCIONALES
MOReFUN
Antonio
Rosales Martínez
Publications by the researcher in collaboration with Antonio Rosales Martínez (16)
2008
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Ti-catalyzed transannular cyclization of epoxygermacrolides. Synthesis of antifungal (+)-tuberiferine and (+)-dehydrobrachylaenolide
Tetrahedron, Vol. 64, Núm. 52, pp. 11938-11943
2007
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Asymmetric Reduction of Ketones
Regio- and Stereo-Controlled Oxidations and Reductions (John Wiley & Sons, Ltd), pp. 87-159
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Erratum: Water: The ideal hydrogen-atom source in free-radical chemistry mediated by TiIII and other single-electron-transfer metals? (Angewandte Chemie - International Edition (2006) 45, (5522-5526) DOI: 10.1002/anie.200600831)
Angewandte Chemie - International Edition
2006
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An improved synthesis of Kagan's menthyl substituted titanocene and zirconocene dichloride, comparison of their crystal structures, and preliminary catalyst evaluation
Journal of Organometallic Chemistry
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Catalytic epoxypolyene cyclization via radicals: Highly diastereoselective formal synthesis of puupehedione and 8-epi-puupehedione
Synlett, pp. 927-929
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Transition-metal-catalyzed allylic substitution and titanocene-catalyzed epoxypolyene cyclization as a powerful tool for the preparation of terpenoids
European Journal of Organic Chemistry, pp. 4115-4127
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Water: The ideal hydrogen-atom source in free-radical chemistry mediated by TiIII and other single-electron-transfer metals?
Angewandte Chemie - International Edition, Vol. 45, Núm. 33, pp. 5522-5526
2005
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Efficient and stereoselective synthesis of precursors for epoxypolyene cyclizations via allylic substitutions
Synlett, pp. 1954-1956
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Enantiospecific strategy towards oxygen-bridged terpenoids: Tandem transannular-cyclization and ring-contraction processes
Angewandte Chemie - International Edition, Vol. 44, Núm. 2, pp. 319-322
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Titanocene-catalysed transannular cyclisation of epoxygermacrolides: Enantiospecific synthesis of eudesmanolides
Catalysts for Fine Chemical Synthesis: Metal Catalysed Carbon-Carbon Bond-Forming Reactions (wiley), pp. 196-200
2004
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Titanocene-Catalyzed Cascade Cyclization of Epoxypolyprenes: Straightforward Synthesis of Terpenoids by Free-Radical Chemistry
Chemistry - A European Journal, Vol. 10, Núm. 7, pp. 1778-1788
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Unprecedented Barbier-type reactions catalysed by titanocene(III)
Chemical Communications, pp. 2628-2629
2003
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Titanocene-catalysed, selective reduction of ketones in aqueous media. A safe, mild, inexpensive procedure for the synthesis of secondary alcohols via radical chemistry
Tetrahedron Letters, Vol. 44, Núm. 5, pp. 1079-1082
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Unified synthesis of eudesmanolides, combining biomimetic strategies with homogeneous catalysis and free-radical chemistry
Organic Letters, Vol. 5, Núm. 11, pp. 1935-1938
2002
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Bioactive metabolites from a marine-derived strain of the fungus Emericella variecolor
Journal of Natural Products, Vol. 65, Núm. 3, pp. 364-367
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Effects of solvents and water in Ti(III)-mediated radical cyclizations of epoxygermacrolides. Straightforward synthesis and absolute stereochemistry of (+)-3α-hydroxyreynosin and related eudesmanolides
Journal of Organic Chemistry, Vol. 67, Núm. 8, pp. 2566-2571